Surprising coordination for low-valent actinides resembling uranyl(vi) in thorium(iv) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology.
نویسندگان
چکیده
Three thorium(iv)-based metal-organic hybrid compounds with 2D layered and 3D framework structures exhibiting graphene-like (6,3) sheet topologies were prepared with linkers with threefold symmetry. These compounds contain rare and relatively anisotropic coordination environments for low-valent actinides that are similar to those often observed for high-valent actinide ions.
منابع مشابه
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عنوان ژورنال:
- Dalton transactions
دوره 45 3 شماره
صفحات -
تاریخ انتشار 2016